15.10.2006
Getafe CF [1 - 0] Real Madrid 1-0 Alexis
Atletico Madrid [2 - 1] Recreativo Huelva 0-1 Guerrero 1-1 Torres 2-1 Agüero
Real Betis Sevilla [1 - 1] Deportivo La Coruna 0-1 Arizmendi 1-1 Robert
FC Barcelona [3 - 1] FC Sevilla 1-0 Ronaldinho 1-1 Kanoute 2-1 Ronaldinho 3-1 Messi
Celta de Vigo [3 - 2] Valencia CF 0-1 Navarro 1-1 Baiano 2-1 Iriney 3-1 Cannobio 3-2 Morientes
FC Villarreal [0 - 0] Espanyol Barcelona
Gimnastic [2 - 3] Athletic Bilbao 0-1 Yeste 0-2 Iraola 0-3 Yeste 1-3 Sarriegi (ET) 2-3 Makukula
Levante UD [0 - 1] RCD Mallorca 0-1 Arango
CA Osasuna [0 - 1] Racing Santander 0-1 Valdo
Real Sociedad [1 - 3] Real Zaragoza 1-0 Prieto 1-1 D. Milito 1-2 Diogo 1-3 D. Milito