22.10.2006
Deportivo La Coruna [1 - 0] Atletico Madrid 1-0 Arizmendi
FC Villarreal [1 - 1] UD Levante 0-1 Camacho 1-1 Jonathan
Real Zaragoza [2 - 1] Real Betis Sevilla 1-0 & 2-0 Milito 2-1 Robert
Athletic Bilbao [0 - 1] Celta de Vigo 0-1 Baiano
Espanyol Barcelona [2 - 2] Racing Santander 0-1 Muntis 1-1 Tamudo 1-2 Chica (ET) 2-2 Tamudo (Pen)
RCD Mallorca [0 - 0] Real Sociedad
Recreativo Huelva [1 - 2] Getafe CF 0-1 Pachon 1-1 Sinama-Pongolle 1-2 Moral
FC Sevilla [2 - 1] Gimnastic 1-0 & 2-0 Kanoute 2-1 Cuellar
Valencia CF [1 - 0] CA Osasuna 1-0 Villa
Real Madrid [2 - 0] Barcelona CF 1-0 Raul 2-0 van Nistelrooy